* Pressing Alt-PrintScreen places an image of the frontmost window on the clipboard. Pressing PrintScreen by itself places an image of the entire desktop on the clipboard.
* Open MS-Paint. (From Start/Run, issue the command "mspaint".) Create a new empty image, and use Edit/Paste to bring in the screenshot you just took. (If the screenshot is smaller than the default Paint canvas, you'll end up with white areas. Start over: create a new empty image, change its dimensions to 1x1, and Paste again. The canvas will grow for the Paste, but it doesn't shrink.)
* Use MS-Paint to Save As, using PNG as the file format
How Do I Take a Screenshot?