There should be on problems in doing that, you may have to take ownership of the files though on the other machine in order to access them (otherwise all your folders will be there but they will show that they are empty and may get access is denied errors.)
To do so if necessary, make sure simple file sharing is disabled to do so:
Open pretty well any folder that gives you an explorer window
Click the Tools menu then Folder Options.
You should see a tab near the top of the resulting window called View...click it.
In the box with all the checkboxes...scroll down to the bottom and uncheck simple file sharing.
Instead of clicking OK. make sure you click on "apply to all folders" near the top of the window, then click ok.
Then once you have the drive installed and set as a slave, right click it and select properties. Then click on the Security tab. Click on advanced and find the option to replace owner, make sure the apply to all child folders option is checked, hit ok and let it do it's thing.
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