Have a look in controll panel for "audioHQ" , you may have to press "other control panel options" at the left side.
Or maybe there is a switch on the external card itself?
I cant find much info on creative's site but that card does have a stereo and a 5.1 channel mode.
So you will have to set it to 5.1.
up to 48kHz in 5.1 mode and up to 96kHz in stereo mode.