HI there Callistra,
Welcome to The Site,
I think that the temps are probably 1-
CPU, 2- ambient (the case temp) and 3 - possibly the VGA card, none of them seem too far out, the vga cards I've seen tend to run at 60-65.
It might be worth checking the airflow around the vga card as this can help bring the temps down a bit.
Hope that helps