If you have a green light on the motherboard, and there is enough power on the
PSU, it would suggest that the new
PSU is good.
You need to ask what has blown the
PSU in the first place. A power surge? (is the PC protected with surge protection)?
How did you determine that there is now power coming from the 4pin molex connector? (A multimeter for example?) Is there any smell of burning around the
CPU area? Is there any sign of leakage from any of the capacitors on board the motherboard?