Well the 4 slots on your motherboard are likely to handle the same spec, so if one is a PC800 slot, then the rest are more than likely to be the same.
You can put 2x64 and 2x128's if you like, but try to stick with the Samsung chips if you can for the 64's, as they are slightly more reliable than MSI and come with heatsinks.
Most shops have stopped selling these, but when you buy the extra 128's, make sure they give you a reliable brand such as Kingston, Corsair or OCZ, and certainly don't accept unbranded memory, as these can become unreliable.
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