What Windows version is this?
Also, personally, I would recommend against it. Even people running exactly the same cards in SLi come up against problems that are sometimes un-fixable. You're suggesting mixing NVidia and ATI cards and drivers together...and on a native NVidia motherboard...hmmm....good luck
The only time I would even
attempt this would be when I absolutely had to have multi monitor support over and above the existing resources available on the current single VGA card.
You must have a really good reason to go thru this?