Sounds like you want to make two new windows paste the image you want into one and start your new image as your background that you want it onto, ctrl + A to select all of the image you want to copy over then go over to the background image and ctrl + V to paste it in, I think that's what you wanted
You can copy your images from the web and paste them into blank documents, just right click the image and press copy and press paste on the photoshop document you have open or press ctrl + V. Alternatively you can save the images somewhere and open them up from Photoshop.
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