Thanks
AW_3_3 
. I already ran Diskeeper, and it did say there was some fragmentation the drive, and after a defrag, the computer was a bit more sprightly, but still not quite as quick as I'd like.
I'm going to try what you said about the IDE channel, as I did have an IDE DVD drive, and have since swapped it out with a SATA one, but put an ATA hard drive on the IDE channel instead.
With both, when the computer starts, there's a black screen which lists all the IDE devices, and says 'Press any key to continue'. I'm guessing this has something to do with why the computer is running slowly.