howdy chessman
Any
mobo/rig can use dual rail power supplys - it just ensures that your power delivery is more linear by allowing one rail to supply power to your video card and processor for example, while the second rail is dedicated to supplying power to your hard drives, add in cards and optical drives
I've got the Xconnect 550 and Antec Neo Power in my two rigs, both have dual rail power supplys and it allowed me higher overclocking as well as better stability at high overclocks in comparison to my old antec and enermax units that were rated for nearly teh same power output, but offered only single rail 12V lines.